COPPER(I)-MEDIATED OXYGENATION OF DITERPENOIDS - 3 ROUTES TO CATECHOL DERIVATIVES

被引：8

作者：

BENDALL, JG ^{[1
]}

CAMBIE, RC ^{[1
]}

RUTLEDGE, PS ^{[1
]}

STEVENSON, RJ ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,PRIVATE BAG 92019,AUCKLAND,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1994年 / 47卷 / 03期

关键词：

D O I：

10.1071/CH9940487

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Derivatives of totarol (1) and podocarpic acid (8) have been oxygenated in ring c via their corresponding carbamates, or aryl bromides, to form catechol derivatives. These oxygenations have been accomplished by the use of copper(i), both in stoichiometric and in catalytic quantities.

引用

页码：487 / 499

页数：13

共 20 条

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