ORGANOMETALLIC CHEMISTRY OF DIPHOSPHAZANES .7. PLATINUM(II), PALLADIUM-(0), PALLADIUM-(I) AND PALLADIUM-(II) COMPLEXES OF RN[P(OPH)2]2 (R = ME OR PH)

被引：45

作者：

BALAKRISHNA, MS ^{[1
]}

KRISHNAMURTHY, SS ^{[1
]}

MURUGAVEL, R ^{[1
]}

NETHAJI, M ^{[1
]}

MATHEWS, II ^{[1
]}

机构：

[1] INDIAN INST SCI, DEPT INORGAN & PHYS CHEM, BANGALORE 560012, KARNATAKA, INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 03期

关键词：

D O I：

10.1039/dt9930000477

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [MCl2(cod)] (M = Pd or Pt, cod = cycloocta-1,5-diene) with RN[P(OPh)2]2 [R = Me (L1) or Ph (L2)] afford the chelate complexes [MCl2L1] and [MCl2L2]. The dinuclear palladium(0) complex, [Pd2L1(3)] has been synthesized by starting from [Pd2(dba)3] (dba = dibenzylideneacetone). Redox condensation of [Pd2(dba)3] and [PdCl2(PhCN)2] in the presence of the diphosphazane ligands gives the dinuclear palladium(I) complexes [Pd2Cl2L12] and [Pd2Cl2L22]. The structures of the complexes have been deduced from H-1 and P-31 NMR spectroscopic data. Single-crystal X-ray diffraction studies confirm the structures of [Pd2L1(3)] and [Pd2Cl2L22].

引用

页码：477 / 482

页数：6

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