A MODEL INTERMEDIATE FOR THE NUCLEOPHILIC-SUBSTITUTION OF (CP)2SN - SYNTHESIS AND STRUCTURE OF (CP)(ME3SI)2NSN(MU-CP)LI.PMDETA [CP = C5H5, PMDETA = (ME2NCH2CH2)2NME]

被引:26
作者
PAVER, MA
RUSSELL, CA
STALKE, D
WRIGHT, DS
机构
[1] INST ANORGAN CHEM,TAMMANNSTR 4,D-37077 GOTTINGEN,GERMANY
[2] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND
关键词
D O I
10.1039/c39930001349
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of LiN(SiMe3)2 with Cp2Sn and pmdeta produces (Cp)(Me3Si)2NSn(mu-Cp)Li.pmdeta 1 which can be viewed as a model intermediate for nucleophilic substitution of Cp2Sn.
引用
收藏
页码:1349 / 1350
页数:2
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