THE HIGH-PRESSURE DIELS-ALDER REACTION OF [5,6]-FULLERENE-C60 WITH CYCLOHEPTATRIENE - FORMATION OF DIELS-ALDER ADDUCTS WITH IMPROVED THERMAL-STABILITY

被引：11

作者：

LIU, JF

KATO, N

MORI, A

TAKESHITA, H

ISOBE, R

机构：

[1] KYUSHU UNIV, GRAD SCH ENGN SCI, KASUGA, FUKUOKA 816, JAPAN

[2] KYUSHU UNIV, FAC PHARMACEUT SCI, HIGASHI KU, FUKUOKA 812, JAPAN

[3] KYUSHU UNIV, INST ADV MAT STUDY, KASUGA, FUKUOKA 816, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 05期

关键词：

D O I：

10.1246/bcsj.67.1507

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The high-pressure Diels-Alder reaction Of C60 with cycloheptatriene under 300 MPa gave two [4+2] cycloadducts derived from two valence isomers, cycloheptatriene and norcaradiene. The thermolysis of the adducts indicated the tricyclo[3.2.2.0(2,4)]non-6-ene derivative is a kinetically-controlled product.

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页码：1507 / 1509

页数：3

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