SYNTHESIS AND OPTICAL SPECTROSCOPY OF MONOMERIC AND POLYMERIC COBALT SIGMA-ACETYLIDE COMPLEXES

被引：26

作者：

KHAN, MS

PASHA, NA

KAKKAR, AK

RAITHBY, PR

LEWIS, J

FUHRMANN, K

FRIEND, RH

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV CAMBRIDGE,CAVENDISH LAB,CAMBRIDGE CB3 0HE,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 07期

关键词：

SIGMA-ACETYLIDE; PI-ELECTRON CONJUGATION; ENERGY GAP; OPTICAL ABSORPTION;

D O I：

10.1039/jm9920200759

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Optical spectra of the complexes, trans-ClCoN4C=CC6H5, trans-CoN4(C=CC6H5)2 and [-CoN4C=C-p-C6H4C=C-]n, (where N4=3,9-dimethyl-4,8-diazaundecane-2,10-dione dioxime) show absorptions associated with pi-pi* transitions of the acetylenic unit and indicate an extended pi-electron conjugation through the metal sites on the chain in the polymeric complex.

引用

页码：759 / 760

页数：2

共 13 条

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