GROUP-TRANSFER ADDITION-REACTIONS OF SELENOMALONONITRILES TO CHIRAL ENOL ETHERS - ASYMMETRIC RADICAL-ADDITION AND SELENIUM TRANSFER-REACTIONS

被引：20

作者：

CURRAN, DP

GEIB, SJ

KUO, LH

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(00)73400-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Group transfer addition reactions of alkyl phenylselenomalononitriles to enol ethers derived from trans-2-phenylcyclohexanol and 8-phenylmenthol occur cleanly, and moderate to excellent stereoselection is observed in both the radical addition and phenylselenium transfer steps.

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收藏

页码：6235 / 6238

页数：4

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