CARBON AND HYDRIDE MIGRATIONS OF CYCLOBUTYLHALOCARBENES

被引：32

作者：

MOSS, RA

HO, GJ

机构：

[1] Department of Chemistry, Rutgers, State University of New Jersey, New Brunswick, New Jersey

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1993年 / 6卷 / 02期

关键词：

D O I：

10.1002/poc.610060210

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photolysis of cyclobutylchlorodiazirine affords chlorocyclopentene and chloromethylenecyclobutane by direct rearrangements from the diazirine's excited state (65%) and by competitive formation and subsequent rearrangement of cyclobutylchlorocarbene. The involvement of excited diazirine in the analogous cyclobutylfluorodiazirine photolysis is much reduced (12%).

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页码：126 / 131

页数：6

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