ALPHA-AMINOPHOSPHONATE DERIVATIVES AS NUCLEOPHILES IN DIASTEREOSELECTIVE AND ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION-REACTIONS

被引：41

作者：

BALDWIN, IC

WILLIAMS, JMJ

BECKETT, RP

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

[2] BRITISH BIOTECH PHARMACEUT LTD,OXFORD OX4 5LY,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 03期

关键词：

D O I：

10.1016/0957-4166(95)00059-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The palladium catalysed reaction between allyl acetates and Schiff base derivatives of alpha-aminophosphonates is reported. For suitable substrates, the observed diastereoselectivities (up to 87:13) and enantioselectivities (>96% eel are high.

引用

页码：679 / 682

页数：4

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