CONVERSION OF ETHANE TO METHANOL AND ETHANOL BY OZONE SENSITIZED PARTIAL OXIDATION AT NEAR ATMOSPHERIC-PRESSURE

被引：3

作者：

GESSER, HD

ZHU, G

HUNTER, NR

机构：

[1] Department of Chemistry, University of Manitoba, Winnipeg

来源：

CATALYSIS TODAY | 1995年 / 24卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0920-5861(95)00053-I

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The reaction of ethane-oxygen mixtures with ozone as a sensitizer in the feed-gas was quantitatively studied at near atmospheric pressure in a dual-flow system. Ozone was generated by silent discharge. The influence of reaction temperature, oxygen concentration in the feed-gas, residence time in the reactor, and ozone concentration in oxygen on the reaction were investigated. Ethanol selectivities (based on carbon) between 3.95 and 21.8% and methanol selectivities between 17.1 and 41.0% with the combined formaldehyde-acetaldehyde-methanol-ethanol (FAME) selectivities between 36.7 and 95.7% were observed for ethane conversion equal to or less than 6.1%. The FAME selectivity was found to be over 90% when the ethane conversion was below 3.5%.

引用

页码：321 / 325

页数：5

共 10 条

[1] KINETICS OF ETHANE OXIDATION [J].