THE ENANTIOSELECTIVE ADDITION OF DIALKYLPHOSPHITES TO ALDEHYDES - CATALYSIS BY A LANTHANUM BINAPHTHOXIDE COMPLEX

被引：127

作者：

RATH, NP ^{[1
]}

SPILLING, CD ^{[1
]}

机构：

[1] UNIV MISSOURI ST LOUIS,DEPT CHEM,ST LOUIS,MO

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)76517-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum (R)-binaphthoxide complex to give (S)-hydroxy phosphonates in good yield and modest enantioselectivity.

引用

页码：227 / 230

页数：4

共 34 条

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[32] ENANTIOSELECTIVITY FOR HYDROPHOSPHONYLATION OF AROMATIC-ALDEHYDES CATALYZED BY LANTHANUM BINAPHTHOL COMPLEX - REMARKABLE ELECTRONIC EFFECT OF AROMATIC SUBSTITUENTS
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[33] ENANTIOSELECTIVE HYDROPHOSPHONYLATION OF AROMATIC-ALDEHYDES CATALYZED BY CHIRAL TITANIUM ALKOXIDES
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[J]. TETRAHEDRON-ASYMMETRY, 1993, 4 (08) : 1779 - 1782
[34] ENANTIOSELECTIVE SYNTHESIS OF ALPHA-AMINO PHOSPHONIC-ACIDS BY AN APPLICATION OF STEREOSELECTIVE OPENING OF HOMOCHIRAL DIOXANE ACETALS WITH TRIETHYL PHOSPHITE
YOKOMATSU, T
SHIBUYA, S
[J]. TETRAHEDRON-ASYMMETRY, 1992, 3 (03) : 377 - 378

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