FLUORINATED VINYL CARBAMATES AND CARBAMOYLOXY ALLYLSILANES - ALPHA-METALATION, ORGANOLITHIUM ADDITION-ELIMINATION, AND FLUORIDE-MEDIATED ELECTROPHILIC REACTIVITY PATTERNS

被引：52

作者：

LEE, J ^{[1
]}

TSUKAZAKI, M ^{[1
]}

SNIECKUS, V ^{[1
]}

机构：

[1] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 03期

关键词：

D O I：

10.1016/0040-4039(93)85090-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

LiTMP or LDA-mediated in situ generation of alpha-lithio difluorovinyl carbamate 1b allows the preparation of silylated derivatives 4a and 2b which undergo organolithium addition-elimination and fluoride-mediated condensation reactions respectively to give new functionalized organofluorine derivatives 5a-d (Table 2) and 11a-c (Table 3).

引用

页码：415 / 418

页数：4

共 20 条

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