CONVENIENT ONE-POT SYNTHESIS OF TERT-BUTYLDIMETHYLANTIMONY

被引：9

作者：

GEDRIDGE, RW

机构：

[1] Chemistry Division, Research Department, Naval Weapons Center, California 93555, China Lake

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 02期

关键词：

D O I：

10.1021/om00038a072

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

tert-Butyldimethylantimony, (t-Bu)Me2Sb, was prepared by a one-pot reaction of SbCl3 with 1 equiv of (t-Bu)MgCl at -50-degrees-C followed by 2 equiv of MeMgBr at 0-degrees-C in diethyl ether. (t-Bu)Me2Sb was isolated in 64 % yield (based on SbCl3) after fractional vacuum distillation (63-degrees-C at 30 Torr) and can be used as a precursor in the chemical vapor deposition of antimony-containing semiconductor materials.

引用

页码：967 / 969

页数：3

共 25 条

[1]

BIEFELD RM, 1990, APPL PHYS LETT, V57, P1563, DOI 10.1063/1.103354

[2] DOPING AND P-N-JUNCTION FORMATION IN INAS1-XSBX/INSB SLSS BY MOCVD [J].