TE-8(4+) - A CUBIC POLYCATION IN THE STRUCTURE OF TE-8(VOCL4)(2)

被引：23

作者：

BECK, J

BOCK, G

机构：

[1] Institut für Anorganische und Analytische Chemie, Universität Giessen, D-35392

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

MAIN GROUP ELEMENT CLUSTERS; POLYCATIONS; SOLID-STATE STRUCTURES TELLURIUM COMPOUNDS;

D O I：

10.1002/anie.199525591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A distorted cube or two four‐membered rings linked through two bonds are alternative descriptive of the tellurium polycation Te 84+ (shown on the right) in Te8(VOCl4)2 1. The Te 84+ and VOCl 42− ions in 1 both form one‐dimensional chains. The Te8 cube can be derived from the α‐Po structure or from paired Te 42+ ions. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2559 / 2561

页数：3

共 23 条

[1]

BECK J, 1990, ANGEW CHEM, V0102

[2]

BECK J, 1994, ANGEW CHEM INT EDIT, V33, P163, DOI 10.1002/anie.199401631

[3] TELLURIUM CATIONS STABILIZED BY NIOBIUM OXYTRIHALIDES - SYNTHESIS AND CRYSTAL-STRUCTURE OF TE7NBOBR5 AND TE7NBOCL5 [J].