THE CONFINEMENT OF HYDROGEN IN LANI5 BY POISONING OF THE HYDRIDE SURFACE

被引：26

作者：

SAKAGUCHI, H ^{[1
]}

TSUJIMOTO, T ^{[1
]}

ADACHI, GY ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1995年 / 223卷 / 01期

关键词：

HYDROGEN STORAGE; HYDRIDES; CARBON MONOXIDE; ADSORPTION; POISONING;

D O I：

10.1016/0925-8388(94)01489-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Surface treatment with CO gas was found to contribute to the confinement of hydrogen in hydrogenated LaNi5. The confinement of hydrogen was enhanced by extension of the CO treatment time and by lowering the temperature at which the sample stood in air. Fourier transform IR spectra suggested that CO molecules chemisorbed on the surface of precipitated Ni which is considered to play the role of recombination center of hydrogen atoms. Since the pathway for hydrogen desorption is sealed by chemisorbed CO molecules, hydrogen appears to be confined in LaNi5. It was found that one chemisorbed CO molecule can confine ca. 10(4) molecules of hydrogen when the average diameter of LaNi, particles is about 3.6 mu m.

引用

页码：122 / 126

页数：5

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