DETERMINATION OF ENANTIOMERIC PURITY OF HYDROXY BIARYLS USING H-1 AND P-31-NMR ON THEIR DIAZAPHOSPHOLIDINE DERIVATIVES

被引：17

作者：

ALEXAKIS, A ^{[1
]}

FRUTOS, JC ^{[1
]}

MANGENEY, P ^{[1
]}

MEYERS, AI ^{[1
]}

MOORLAG, H ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)77044-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral biaryl alcohols were readily transformed in a single step, with chiral nonracemic 1,2-diamines, PCl3, and sulfur in CDCl3 - all in a NMR tube - to their diastereomeric diazaphospholidines and their diastereomeric ratios (also ee's) assessed directly.

引用

收藏

页码：5125 / 5128

页数：4

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