REACTIONS OF ETA(2)-(2-ACYLARYL-C,O)TETRACARBONYLMANGANESE(I) COMPLEXES WITH SOME VINYL SULFUR-COMPOUNDS

被引：7

作者：

CAMBIE, RC ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WELCH, DR ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,PRIVATE BAG 92019,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 467卷 / 02期

关键词：

SULFUR; VINYL; MANGANESE; CARBONYL;

D O I：

10.1016/0022-328X(94)80011-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermally promoted reactions of some phenyl and diterpenoid eta2-(2-acylaryl-C,O)tetracarbonylmanganese(I) complexes with phenyl vinyl sulfone, methyl vinyl sulfone, or phenyl vinyl sulfoxide, have been investigated. The major products from the diterpenoid complexes arise from insertion followed by reductive demetallation; cyclopenta-annulation, when it occurs, is a minor process. Liberation of the metal-free adducts from their Mn-containing precursors requires treatment with either acid or photolysis-oxidation.

引用

页码：237 / 244

页数：8

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