NOVEL LEWIS-ACID CATALYSIS IN ORGANIC-SYNTHESIS

被引：42

作者：

SUZUKI, K

机构：

[1] Department of Chemistry, Keio University, Yokohama 223

来源：

PURE AND APPLIED CHEMISTRY | 1994年 / 66卷 / 07期

关键词：

D O I：

10.1351/pac199466071557

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic zirconocene or hafnocene complexes serve as a novel class of Lewis acid with unique reactivities, which are to be exploited in organic synthesis. Four categories of reactivities are discussed, that is, (A) C-F bond activation/cleavage, (B) Coordinative activation of ether linkages, (C) Carbonyl activation, and (D) C-O bond cleavage via zirconocene alkoxide.

引用

收藏

页码：1557 / 1564

页数：8

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