Trends in selenium determination/speciation by hyphenated techniques based on AAS or AFS

被引:68
作者
Capelo, JL [1 ]
Fernandez, C
Pedras, B
Santos, P
Gonzalez, P
Vaz, C
机构
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, REQUIMTE, P-2829516 Monte De Caparica, Portugal
[2] Inst Super Tecn, Lab Anal IST, P-1049001 Lisbon, Portugal
关键词
selenium speciation; hyphenated techniques; AAS; AFS;
D O I
10.1016/j.talanta.2005.08.027
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The field of selenium speciation has been studied for decades and the growing interest in this field seems never to reach a plateau. Although powerful techniques based on mass spectrometry are nowadays used for selenium determination/speciation, few laboratories can support the high cost of such techniques. The hyphenation of chromatography to atomic absorption or atomic fluorescence spectrometry (AAS or AFS) is still a reliable and low-cost alternative for routine laboratories. In this work we present the most important parameters dealing with selenium speciation along with the latest trends in this subject, namely in the items related with sample treatment and hyphenation techniques with AAS and AFS detection. (c) 2005 Elsevier B.V. All rights reserved.
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页码:1442 / 1447
页数:6
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