Preparation of ZnS thin films by the pulsed electrochemical deposition

被引:59
作者
Fathy, N [1 ]
Kobayashi, R [1 ]
Ichimura, M [1 ]
机构
[1] Nagoya Inst Technol, Dept Engn Phys Elect & Mech, Showa Ku, Nagoya, Aichi 4668555, Japan
来源
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2004年 / 107卷 / 03期
关键词
ZnS; electrochemical deposition (ECD); pulse; thin films; solar cells;
D O I
10.1016/j.mseb.2003.11.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We deposited ZnS thin films on Sn-doped In2O3-COated glass substrate using normal and pulsed electrochemical deposition (ECD) from aqueous solutions containing Na2S2O3 and ZnSO4 with two different compositions. Generally, the films deposited using pulsed deposition has much better surface morphology and optical properties than those deposited by normal ECD. The film deposited from the ZnSO4-rich solution was of stoichiometric composition and after 300 degreesC annealing gives high transparency. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:271 / 276
页数:6
相关论文
共 10 条
[1]   PROCESS AND FILM CHARACTERIZATION OF CHEMICAL-BATH-DEPOSITED ZNS THIN-FILMS [J].
DONA, JM ;
HERRERO, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (01) :205-210
[2]   Raman and photoluminescence characterizations of electrochemically deposited ZnxCd1-xS layers [J].
Ichimura, M ;
Furukawa, T ;
Shirai, K ;
Goto, F .
MATERIALS LETTERS, 1997, 33 (1-2) :51-55
[3]   ELECTRODEPOSITIONS OF CDS, ZNS AND CD1-XZNXS FILMS [J].
LOKHANDE, CD ;
YERMUNE, VS ;
PAWAR, SH .
MATERIALS CHEMISTRY AND PHYSICS, 1988, 20 (03) :283-292
[4]   CHARACTERIZATION OF ELECTRODEPOSITED ZINC-SULFIDE THIN-FILMS [J].
MAHALINGAM, T ;
SANJEEVIRAJA, C .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1992, 129 (02) :K89-K92
[5]  
MISHRA K, 1989, J ELECTROCHEM SOC, V136, P7
[6]   Band offset of high efficiency CBD-ZnS/CIGS thin film solar cells [J].
Nakada, T ;
Hongo, M ;
Hayashi, E .
THIN SOLID FILMS, 2003, 431 :242-248
[7]  
Pandy R.K., 1996, HDB SEMICONDUCTOR EL
[8]   Electrodeposition and characterization of ZnSe semiconductor thin films [J].
Riveros, G ;
Gómez, H ;
Henríquez, R ;
Schrebler, R ;
Marotti, RE ;
Dalchiele, EA .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 70 (03) :255-268
[9]   THE ELECTRODEPOSITION OF THIN-FILM ZINC-SULFIDE FROM THIOSULFATE SOLUTION [J].
SANDERS, BW ;
KITAI, AH .
JOURNAL OF CRYSTAL GROWTH, 1990, 100 (03) :405-410
[10]   SnS thin films fabricated by pulsed and normal electrochemical deposition [J].
Takeuchi, K ;
Ichimura, M ;
Arai, E ;
Yamazaki, Y .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2003, 75 (3-4) :427-432