CVD synthesis of mono- and few-layer graphene using alcohols at low hydrogen concentration and atmospheric pressure

被引：31

作者：

Campos-Delgado, Jessica ^{[1
]}

Botello-Mendez, Andres R. ^{[2
]}

Algara-Siller, Gerardo ^{[3
]}

Hackens, Benoit ^{[2
]}

Pardoen, Thomas ^{[4
]}

Kaiser, Ute ^{[3
]}

Dresselhaus, Mildred S. ^{[5
]}

Charlier, Jean-Christophe ^{[2
]}

Raskin, Jean-Pierre ^{[1
]}

机构：

[1] Catholic Univ Louvain, Inst Informat & Commun Technol Elect & Appl Math, B-1348 Louvain, Belgium

[2] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, B-1348 Louvain, Belgium

[3] Univ Ulm, Cent Facil Electron Microscopy, D-89073 Ulm, Germany

[4] Catholic Univ Louvain, Inst Mech Mat & Civil Engn, B-1348 Louvain, Belgium

[5] MIT, Dept Elect Engn & Comp Sci, Cambridge, MA 02139 USA

来源：

CHEMICAL PHYSICS LETTERS | 2013年 / 584卷

基金：

美国国家科学基金会;

关键词：

CHEMICAL-VAPOR-DEPOSITION; LARGE-AREA; COPPER; FILMS; GROWTH; SINGLE;

D O I：

10.1016/j.cplett.2013.08.031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

An original and easy route to produce mono-, bi- and tri-layer graphene is proposed using the chemical vapor deposition technique. The synthesis is carried out at atmospheric pressure using liquid precursors, copper as catalyst, and a single gas injection line consisting of a very diluted mixture of H-2 in Argon (H-2: 5%). Two different alcohols are investigated as possible sources of carbon: 2-phenylethanol and ethanol. The characterization of the samples with SEM, TEM and Raman spectroscopy confirms the presence of graphene on top of copper, and yields a detailed picture of the structure of the produced graphene layers. (c) 2013 Elsevier B.V. All rights reserved.

引用

页码：142 / 146

页数：5

共 24 条

[1]

Electronic confinement and coherence in patterned epitaxial graphene [J].

Berger, Claire ;

Song, Zhimin ;

Li, Xuebin ;

Wu, Xiaosong ;

Brown, Nate ;

Naud, Cecile ;

Mayou, Didier ;

Li, Tianbo ;

Hass, Joanna ;

Marchenkov, Atexei N. ;

Conrad, Edward H. ;

First, Phillip N. ;

de Heer, Wait A. .

SCIENCE, 2006, 312 (5777) :1191-1196

[2]

Structural coherency of graphene on Ir(111) [J].

Coraux, Johann ;

N'Diaye, Alpha T. ;

Busse, Carsten ;

Michely, Thomas .

NANO LETTERS, 2008, 8 (02) :565-570

[3]

Growth of large-sized graphene thin-films by liquid precursor-based chemical vapor deposition under atmospheric pressure [J].

Dong, Xiaochen ;

Wang, Peng ;

Fang, Wenjing ;

Su, Ching-Yuan ;

Chen, Yu-Hsin ;

Li, Lain-Jong ;

Huang, Wei ;

Chen, Peng .

CARBON, 2011, 49 (11) :3672-3678

[4]

Raman spectrum of graphene and graphene layers [J].

Ferrari, A. C. ;

Meyer, J. C. ;

Scardaci, V. ;

Casiraghi, C. ;

Lazzeri, M. ;

Mauri, F. ;

Piscanec, S. ;

Jiang, D. ;

Novoselov, K. S. ;

Roth, S. ;

Geim, A. K. .

PHYSICAL REVIEW LETTERS, 2006, 97 (18)

[5]

Chemical vapor deposition synthesis of graphene on copper with methanol, ethanol, and propanol precursors [J].

Guermoune, Abdeladim ;

Chari, Tarun ;

Popescu, Filip ;

Sabri, Shadi S. ;

Guillemette, Jonathan ;

Skulason, Helgi S. ;

Szkopek, Thomas ;

Siaj, Mohamed .

CARBON, 2011, 49 (13) :4204-4210

[6]

Large-scale pattern growth of graphene films for stretchable transparent electrodes [J].

Kim, Keun Soo ;

Zhao, Yue ;

Jang, Houk ;

Lee, Sang Yoon ;

Kim, Jong Min ;

Kim, Kwang S. ;

Ahn, Jong-Hyun ;

Kim, Philip ;

Choi, Jae-Young ;

Hong, Byung Hee .

NATURE, 2009, 457 (7230) :706-710

[7]

Wafer Scale Homogeneous Bilayer Graphene Films by Chemical Vapor Deposition [J].

Lee, Seunghyun ;

Lee, Kyunghoon ;

Zhong, Zhaohui .

NANO LETTERS, 2010, 10 (11) :4702-4707

[8]

Evolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling [J].

Li, Xuesong ;

Cai, Weiwei ;

Colombo, Luigi ;

Ruoff, Rodney S. .

NANO LETTERS, 2009, 9 (12) :4268-4272

[9]

Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils [J].

Li, Xuesong ;

Cai, Weiwei ;

An, Jinho ;

Kim, Seyoung ;

Nah, Junghyo ;

Yang, Dongxing ;

Piner, Richard ;

Velamakanni, Aruna ;

Jung, Inhwa ;

Tutuc, Emanuel ;

Banerjee, Sanjay K. ;

Colombo, Luigi ;

Ruoff, Rodney S. .

SCIENCE, 2009, 324 (5932) :1312-1314

[10]

Determination of LA and TO phonon dispersion relations of graphene near the Dirac point by double resonance Raman scattering [J].

Mafra, D. L. ;

Samsonidze, G. ;

Malard, L. M. ;

Elias, D. C. ;

Brant, J. C. ;

Plentz, F. ;

Alves, E. S. ;

Pimenta, M. A. .

PHYSICAL REVIEW B, 2007, 76 (23)

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