Cu(In,Ga)Se2 prepared by a 2 and 3-stage hybrid RF-magnetron sputtering and Se evaporation method:: Properties and solar cell performance

被引:4
作者
da Cunha, A. F. [1 ]
Kurdzesau, F. [1 ]
Salome, P. M. P. [1 ]
机构
[1] Univ Aveiro, Dept Fis, P-3810193 Aveiro, Portugal
来源
ADVANCED MATERIALS FORUM III, PTS 1 AND 2 | 2006年 / 514-516卷
关键词
CIGS; hybrid RF magnetron sputtering; solar cells;
D O I
10.4028/www.scientific.net/MSF.514-516.93
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The potential of RF-magnetron sputtering to achieve high quality Cu(In,Ga)Se-2 (CIGS) thin films and efficient solar cells with the goal of using a single technique for all solar cell processing steps is explored. The end point detection method was adapted to RF-magnetron deposition of CIGS in two- or three stages sputtering process. It allows the control of the final composition of the deposited layers in a reproducible way. The influence of substrate temperature and Ar pressure during the deposition on the surface and crossectional morphology of CIGS films was studied for two and three-stage sputtering process sequence. The solar cells prepared with films deposited by two-stage sputtering nave showed a better performance with maximum efficiency above 8%.
引用
收藏
页码:93 / 97
页数:5
相关论文
共 10 条
[1]   Copper indium disulfide solar cell absorbers prepared in a one-step process by reactive magnetron sputtering from copper and indium targets [J].
Ellmer, K ;
Hinze, J ;
Klaer, J .
THIN SOLID FILMS, 2002, 413 (1-2) :92-97
[2]   PREPARATION OF DEVICE-QUALITY CU(IN,GA)SE-2 THIN-FILMS DEPOSITED BY COEVAPORATION WITH COMPOSITION MONITOR [J].
KOHARA, N ;
NEGAMI, T ;
NISHITANI, M ;
WADA, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1995, 34 (9A) :L1141-L1144
[3]   Improvement of electrical yield in the fabrication of CIGS-based thin-film modules [J].
Kushiya, K .
THIN SOLID FILMS, 2001, 387 (1-2) :257-261
[4]   Cu-based multinary compounds and their crystal growth: synthesis processes, phase diagrams and control of vapor pressures [J].
Matsushita, H ;
Katsui, A ;
Takizawa, T .
JOURNAL OF CRYSTAL GROWTH, 2002, 237 :1986-1992
[5]   Rapid CIS-process for high efficiency PV-modules: development towards large area processing [J].
Probst, V ;
Stetter, W ;
Riedl, W ;
Vogt, H ;
Wendl, M ;
Calwer, H ;
Zweigart, S ;
Ufert, KD ;
Freienstein, B ;
Cerva, H ;
Karg, FH .
THIN SOLID FILMS, 2001, 387 (1-2) :262-267
[6]   Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar cells [J].
Ramanathan, K ;
Contreras, MA ;
Perkins, CL ;
Asher, S ;
Hasoon, FS ;
Keane, J ;
Young, D ;
Romero, M ;
Metzger, W ;
Noufi, R ;
Ward, J ;
Duda, A .
PROGRESS IN PHOTOVOLTAICS, 2003, 11 (04) :225-230
[7]   LATTICE-VIBRATIONS OF CUINSE2 AND CUGASE2 BY RAMAN MICROSPECTROMETRY [J].
RINCON, C ;
RAMIREZ, FJ .
JOURNAL OF APPLIED PHYSICS, 1992, 72 (09) :4321-4324
[8]  
ROCKETT A, 1990, P 21 IEEE PHOT SPEC, P764
[9]   Efficiency enhancement of Cu(In,Ga)Se2 solar cells due to post-deposition Na incorporation [J].
Rudmann, D ;
da Cunha, AF ;
Kaelin, M ;
Kurdesau, F ;
Zogg, H ;
Tiwari, AN ;
Bilger, G .
APPLIED PHYSICS LETTERS, 2004, 84 (07) :1129-1131
[10]   STUDIES OF THE GROWTH-MECHANISM OF POLYCRYSTALLINE CUINSE2 THIN-FILMS PREPARED BY A SEQUENTIAL PROCESS [J].
ZWEIGART, S ;
SCHMID, D ;
KESSLER, J ;
DITTRICH, H ;
SCHOCK, HW .
JOURNAL OF CRYSTAL GROWTH, 1995, 146 (1-4) :233-238