N-heterocyclic carbenes in gold catalysis

被引：666

作者：

Marion, Nicolas ^{[1
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2008年 / 37卷 / 09期

关键词：

D O I：

10.1039/b711132k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The appealing properties of N-heterocyclic carbenes (NHC) as ancillary ligands and the high potential of gold as an organometallic catalyst have made their encounter inevitable. Still in its infancy, NHC-gold catalysis is nevertheless growing rapidly. In this tutorial review, catalytic transformations involving NHC-containing gold(I) and gold(III) complexes are presented. Particular attention is drawn to the versatility and selectivity of these catalysts.

引用

页码：1776 / 1782

页数：7

共 42 条

[1] Reversible C-F bond formation and the Au-catalyzed hydrofluorination of alkynes [J].

Akana, Jennifer A. ;

Bhattacharyya, Koyel X. ;

Mueller, Peter ;

Sadighi, Joseph P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (25) :7736-+

[2] Cationic, linear Au(I) N-heterocyclic carbene complexes:: synthesis, structure and anti-mitochondrial activity [J].

Baker, Murray V. ;

Barnard, Peter J. ;

Berners-Price, Susan J. ;

Brayshaw, Simon K. ;

Hickey, James L. ;

Skelton, Brian W. ;

White, Allan H. .

DALTON TRANSACTIONS, 2006, (30) :3708-3715

[3] Luminescence studies of the intracellular distribution of a dinuclear gold(I) N-heterocyclic carbene complex [J].

Barnard, Peter J. ;

Wedlock, Louise E. ;

Baker, Murray V. ;

Berners-Price, Susan J. ;

Joyce, David A. ;

Skelton, Brian W. ;

Steer, James H. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (36) :5966-5970

[4] Room temperature hydroamination of N-alkenyl ureas catalyzed by a gold(I) N-heterocyclic carbene complex [J].

Bender, Christopher F. ;

Widenhoefer, Ross A. .

ORGANIC LETTERS, 2006, 8 (23) :5303-5305

[5] Coinage metal complexes with N-heterocyclic carbene ligands as selective catalysts in diboration reaction [J].

Corberan, Rosa ;

Ramirez, Jesus ;

Poyatos, Macarena ;

Peris, Eduardo ;

Fernandez, Elena .

TETRAHEDRON-ASYMMETRY, 2006, 17 (12) :1759-1762

[6] New heterogenized gold(I)-heterocyclic carbene complexes as reusable catalysts in hydrogenation and cross-coupling reactions [J].

Corma, A. ;

Gutierrez-Puebla, E. ;

Iglesias, M. ;

Monge, A. ;

Perez-Ferreras, S. ;

Sanchez, F. .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (14) :1899-1907

[7] Gold nanoparticles and gold(III) complexes as general and selective hydrosilylation catalysts [J].

Corma, Avelino ;

Gonzalez-Arellano, Camino ;

Iglesias, Marta ;

Sanchez, Felix .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (41) :7820-7822

[8] Heterogenized gold(I), gold(III), and Palladium(II) complexes for C-C bond reactions [J].

Corma, Avelino ;

Gonzalez-Arellano, Camino ;

Iglesias, Marta ;

Perez-Ferreras, Susana ;

Sanchez, Felix .

SYNLETT, 2007, (11) :1771-1774

[9] Golden carousel in catalysis: The cationic gold/propargylic ester cycle [J].

Correa, Andrea ;

Marion, Nicolas ;

Fensterbank, Louis ;

Malacria, Max ;

Nolan, Steven P. ;

Cavallo, Luigi .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (04) :718-721

[10] Synthesis, characterization and reactivity of N-heterocyclic carbene gold(III) complexes [J].

de Fremont, Pierre ;

Singh, Rohit ;

Stevens, Edwin D. ;

Petersen, Jeffrey L. ;

Nolan, Steven P. .

ORGANOMETALLICS, 2007, 26 (06) :1376-1385

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