Microchip capillary electrophoresis with a single-wall carbon nanotube/gold electrochemical detector for determination of aminophenols and neurotransmitters

被引:54
作者
Pumera, M [1 ]
Llopis, X [1 ]
Merkoçi, A [1 ]
Alegret, S [1 ]
机构
[1] Univ Autonoma Barcelona, Dept Quim, Grp Sensors & Biosensors, E-08193 Barcelona, Catalonia, Spain
关键词
single-wall carbon nanotubes; microchip capillary electrophoresis; electrochemistry; phenols;
D O I
10.1007/s00604-005-0438-0
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new SWCNT modified gold detector for microchip capillary electrophoresis-electrochemistry is described. SWCNT modified gold electrode displays greatly improved sensitivity and separation resolution compared to bare gold electrode, reflecting the electrocatalytic activity of SWCNT. The SWCNT/Au electrode exhibits low background noise levels. Parameters such as separation voltage and detection potential of the microchip electrophoresis-electrochemistry with SWCNT modified gold electrode were optimized.
引用
收藏
页码:261 / 265
页数:5
相关论文
共 40 条
[1]   Electrochemical biosensing platforms using platinum nanoparticles and carbon nanotubes [J].
Hrapovic, S ;
Liu, YL ;
Male, KB ;
Luong, JHT .
ANALYTICAL CHEMISTRY, 2004, 76 (04) :1083-1088
[2]  
Klett O, 2002, ELECTROPHORESIS, V23, P3678, DOI 10.1002/1522-2683(200211)23:21<3678::AID-ELPS3678>3.0.CO
[3]  
2-O
[4]   Electrochemical determination of hydrogen sulfide at carbon nanotube modified electrodes [J].
Lawrence, NS ;
Deo, RP ;
Wang, J .
ANALYTICA CHIMICA ACTA, 2004, 517 (1-2) :131-137
[5]   Simple and sensitive electrode design for microchip electrophoresis/electrochemistry [J].
Liu, Y ;
Vickers, JA ;
Henry, CS .
ANALYTICAL CHEMISTRY, 2004, 76 (05) :1513-1517
[6]   Investigation of the electrochemical and electrocatalytic behavior of single-wall carbon nanotube film on a glassy carbon electrode [J].
Luo, HX ;
Shi, ZJ ;
Li, NQ ;
Gu, ZN ;
Zhuang, QK .
ANALYTICAL CHEMISTRY, 2001, 73 (05) :915-920
[7]   Carbon paste-based electrochemical detectors for microchip capillary electrophoresis/electrochemistry [J].
Martin, RS ;
Gawron, AJ ;
Fogarty, BA ;
Regan, FB ;
Dempsey, E ;
Lunte, SM .
ANALYST, 2001, 126 (03) :277-280
[8]   New materials for electrochemical sensing VI:: Carbon nanotubes [J].
Merkoçi, A ;
Pumera, M ;
Llopis, X ;
Pérez, B ;
del Valle, M ;
Alegret, S .
TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2005, 24 (09) :826-838
[9]   Basal plane pyrolytic graphite modified electrodes: Comparison of carbon nanotubes and graphite powder as electrocatalysts [J].
Moore, RR ;
Banks, CE ;
Compton, RG .
ANALYTICAL CHEMISTRY, 2004, 76 (10) :2677-2682
[10]   Low-potential stable NADH detection at carbon-nanotube-modified glassy carbon electrodes [J].
Musameh, M ;
Wang, J ;
Merkoci, A ;
Lin, YH .
ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (10) :743-746