Synthesis and photophysical characterization of a titanium(IV) phthalocyanine-C60 supramolecular dyad

被引:74
作者
Ballesteros, B
de la Torre, G
Torres, T
Hug, GL
Rahman, GMA
Guldi, DM
机构
[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain
[2] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46566 USA
[3] Univ Erlangen Nurnberg, Inst Phys & Theoret Chem, D-91058 Erlangen, Germany
关键词
phthalocyanine; fullerene; titanium(IV); electron transfer;
D O I
10.1016/j.tet.2005.08.126
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An axially substituted titanium(IV) phthalocyanine-fullerene donor-acceptor supramolecular dyad has been prepared by two different approaches, one of them representing a convenient convergent strategy. The dyad system exhibits photoinduced electron transfer upon irradiation with visible light to produce a microsecond lived charge separated state. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2097 / 2101
页数:5
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