Optimization of click chemistry of ferrocene derivatives on acetylene-functionalized silicon(100) surfaces

被引：62

作者：

Ciampi, Snnone ^{[1
]}

Le Saux, Guillaume ^{[1
]}

Harper, Jason B. ^{[1
]}

Gooding, J. Justin ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

ELECTROANALYSIS | 2008年 / 20卷 / 14期

关键词：

click chemistry; ferrocene; hydrosilylation; redox assemblies; self-assembled monolayers; silicon surfaces;

D O I：

10.1002/elan.200804241

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The optimization of the reaction conditions for copper-catalyzed azide-alkyne 'click' cyclo-addition reactions used to covalently confine substituted ferrocene derivatives on passivated silicon(100) surfaces is reported. Variations in the observed reaction yields and the extent of surface contamination as a function of the source of the copper catalyst and the solvent system used in the 'click' procedure were evaluated spectroscopically. The electronic communication between the ferrocene centre and the underlying semiconductor surface was investigated by means of cyclic voltammetry and found to be consistent with that expected for a well-behaved and robust redox interface.

引用

页码：1513 / 1519

页数：7

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