Selective switchable iron-catalyzed hydrosilylation of carboxylic acids

被引：92

作者：

Castro, Luis C. Misal ^{[1
]}

Li, Haoquan ^{[1
]}

Sortais, Jean-Baptiste ^{[1
]}

Darcel, Christophe ^{[1
]}

机构：

[1] Univ Rennes 1, UMR CNRS 6226, Inst Sci Chim Rennes, Ctr Catalysis & Green Chem Organometall Mat & Cat, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 85期

关键词：

ONE-POT CONVERSION; EFFICIENT HYDROSILYLATION; FACILE REDUCTION; ALDEHYDES; HYDRIDE; COMPLEXES; RUTHENIUM; AMIDES; ISOMERIZATION; CONVENIENT;

D O I：

10.1039/c2cc35727e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective reduction of carboxylic acids either to aldehydes or alcohols is achieved using a one pot procedure based on iron-catalyzed hydrosilylations. Using phenylsilane and (COD)Fe(CO)(3) catalyst under UV-irradiation at rt, alcohols were obtained specifically in good yields, whereas aldehydes were selectively obtained using TMDS and (t-PBO)Fe(CO)(3) catalyst under thermal activation.

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收藏

页码：10514 / 10516

页数：3

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