Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

被引：44

作者：

Hirai, Kenji ^{[2
]}

Furukawa, Shuhei ^{[1
,3
]}

Kondo, Mio ^{[1
,3
]}

Meilikhov, Mikhail ^{[1
,3
]}

Sakata, Yoko ^{[1
,3
]}

Sakata, Osami ^{[4
]}

Kitagawa, Susumu ^{[1
,2
,3
]}

机构：

[1] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[3] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan

[4] Natl Inst Mat Sci, Synchrotron Xray Stn SPring 8, Sayo, Hyogo 6795198, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 52期

关键词：

METAL-ORGANIC FRAMEWORK; SEPARATION; ADSORPTION; ANTHRACENE; COMPLEXES; DESIGN; AMINES;

D O I：

10.1039/c2cc31421e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spatiospecific functionalisation of a shell crystal was performed in a core-shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.

引用

页码：6472 / 6474

页数：3

共 35 条

[31] Characterization of photoinduced electron transfer in jet-formed acceptor-donor complexes.: 1.: Isomeric forms of complexes of anthracene with aniline derivatives [J].

Tramer, A ;

Brenner, V ;

Millié, P ;

Piuzzi, F .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (17) :2798-2807

[32] Tandem modification of metal-organic frameworks by a postsynthetic approach [J].

Wang, Zhenqiang ;

Cohen, Seth M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (25) :4699-4702

[33] INFRARED STUDIES OF COMPLEXES BETWEEN CARBOXYLIC-ACIDS AND TERTIARY-AMINES IN ARGON MATRICES [J].

WIERZEJEWSKAHNAT, M ;

MIELKE, Z ;

RATAJCZAK, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1980, 76 :834-843

[34] Homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis [J].

Wu, CD ;

Hu, A ;

Zhang, L ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (25) :8940-8941

[35] Reticular synthesis and the design of new materials [J].

Yaghi, OM ;

O'Keeffe, M ;

Ockwig, NW ;

Chae, HK ;

Eddaoudi, M ;

Kim, J .

NATURE, 2003, 423 (6941) :705-714

← 1 2 3 4 →