A Metal-Free, Lithium-Ion Oxygen Battery: A Step Forward to Safety in Lithium-Air Batteries

被引：148

作者：

Hassoun, Jusef ^{[1
]}

Jung, Hun-Gi ^{[2
]}

Lee, Dong-Ju ^{[2
]}

Park, Jin-Bum ^{[2
]}

Amine, Khalil ^{[3
]}

Sun, Yang-Kook ^{[2
]}

Scrosati, Bruno ^{[1
]}

机构：

[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy

[2] Hanyang Univ, Dept WCU Energy Engn, Seoul 133791, South Korea

[3] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

来源：

NANO LETTERS | 2012年 / 12卷 / 11期

关键词：

Lithium-ion oxygen cell; lithiated silicon-carbon anode; reversible charge-discharge process; rechargeable lithium metal-free-air battery; SOLID-STATE;

D O I：

10.1021/nl303087j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A preliminary study of the behavior of lithium-ion-air battery, where the common, unsafe lithium metal anode is replaced by a lithiated silicon-carbon composite, is reported. The results based on X-ray diffraction and galvanostatic charge-discharge analyses, demonstrate, the basic reversibility of the electrochemical process of the battery that can be promisingly cycled with a rather high specific capacity.

引用

页码：5775 / 5779

页数：5

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