Fabrication of polyaniline with hierarchical structures in alkaline solution

被引：45

作者：

Zhou, Chuanqiang ^{[1
]}

Han, Jie ^{[1
]}

Song, Genping ^{[1
]}

Guo, Rong ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

来源：

EUROPEAN POLYMER JOURNAL | 2008年 / 44卷 / 09期

关键词：

Hierarchical structures; NaOH; Oxidation polymerization; Polyaniline;

D O I：

10.1016/j.eurpolymj.2008.01.025

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nanosheet- or nanorod-based microspheres and nanorod-based microrods of polyaniline (PANI) with hierarchical structures were successfully prepared by oxidation polymerization of aniline in alkaline solution. Temperature was found to have important influence on the morphology of PANI hierarchical structures and their building blocks. The concentration of alkali (NaOH) could be used to guide the morphological evolution of PANI, from leaf-like structures to nanosheet-based particles, and to nanorod-based microspheres and nanorod-based microrods with increasing concentration of NaOH in synthesis. The chemical structures of product were characterized by FTIR, UV-vis spectra and XRD, and its solubility was also studied in this report. (C) 2008 Published by Elsevier Ltd.

引用

页码：2850 / 2858

页数：9

共 37 条

[11] Synthesis of nanostructured large particles of polyaniline [J].

Eftekhari, Ali .

JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (06) :6060-6063

[12] THERMOCHEMISTRY AND KINETICS OF CHEMICAL POLYMERIZATION OF ANILINE DETERMINED BY SOLUTION CALORIMETRY [J].

FU, YP ;

ELSENBAUMER, RL .

CHEMISTRY OF MATERIALS, 1994, 6 (05) :671-677

[13] Nanofiber formation in the chemical polymerization of aniline: A mechanistic study [J].

Huang, JX ;

Kaner, RB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (43) :5817-5821

[14] Polyaniline nanofibers: Facile synthesis and chemical sensors [J].

Huang, JX ;

Virji, S ;

Weiller, BH ;

Kaner, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (02) :314-315

[15] Polyaniline nanowires by electropolymerization from liquid crystalline phases [J].

Huang, LM ;

Wang, ZB ;

Wang, HT ;

Cheng, XL ;

Mitra, A ;

Yan, YS .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (02) :388-391

[16] Microtubule sensors and sensor array based on polyaniline synthesized in the presence of poly(styrene sulfonate) [J].

Kanungo, M ;

Kumar, A ;

Contractor, AQ .

ANALYTICAL CHEMISTRY, 2003, 75 (21) :5673-5679

[17] Synthesis of radially aligned polyaniline dendrites [J].

Li, GC ;

Pang, SP ;

Xie, GW ;

Wang, ZB ;

Peng, HR ;

Zhang, ZK .

POLYMER, 2006, 47 (04) :1456-1459

[18] Preparation of a nanowire-structured polyaniline composite and gas sensitivity studies [J].

Ma, XF ;

Li, G ;

Wang, M ;

Cheng, YN ;

Bai, R ;

Chen, HZ .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (12) :3254-3260

[19]

MacDiarmid AG, 2001, ANGEW CHEM INT EDIT, V40, P2581, DOI 10.1002/1521-3773(20010716)40:14<2581::AID-ANIE2581>3.0.CO

[20]

2-2

← 1 2 3 4 →