Self-assembly with block copolymers through metal coordination of SCS-PdII pincer complexes and pseudorotaxane formation

被引：49

作者：

South, Clinton R. ^{[1
]}

Higley, Mary Nell ^{[1
]}

Leung, Ken C. -F. ^{[1
]}

Lanari, Daniela ^{[1
]}

Nelson, Alshakim ^{[1
]}

Grubbs, Robert H. ^{[1
]}

Stoddart, J. Fraser ^{[1
]}

Weck, Marcus ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Lab Chem Synth, 1200 E Calif Blvd, Pasadena, CA 91125 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2006年 / 12卷 / 14期

关键词：

copolymerization; crown compounds; palladium; pincer complexes; supramolecular; chemistry;

D O I：

10.1002/chem.200501028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(norbornene)-based block copolymers containing side chains of palladated pincer complexes/dibenzo[24]crown-8 or palladated pincer complexes/dibenzylammonium salts were synthesized. Noncovalent functionalization was accomplished with their corresponding recognition units through simple 1:1 addition with association constants (K-a) greater than 10(5) m(-1). The self-assembly processes were monitored by using both H-1 NMR spectroscopy and isothermal titration calorimetry. In all cases, we found that the self-assembly of the recognition units along each polymer block does not preclude the self-assembly processes along the other block.

引用

页码：3789 / 3797

页数：9

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