Lanthanide-transition-metal sandwich framework comprising {Cu3} cluster pillars and layered networks of {Er36}) wheels

被引：332

作者：

Cheng, JW ^{[1
]}

Zhang, J ^{[1
]}

Zheng, ST ^{[1
]}

Zhang, MB ^{[1
]}

Yang, GY ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 01期

关键词：

bridging ligands; cluster compounds; copper; hydrothermal synthesis; lanthanides;

D O I：

10.1002/anie.200502917

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synergistic coordination between isonicotinate (ina) and 1,2-benzenedicarboxylate (bdc) ligands under hydrothermal conditions results in the formation of two new coordination polymers, [Er7(μ 3-O)(μ3-OH)6(bdc)3](ina) 9[Cu3X4] (X = Cl, Br). Wheel-shaped [Er 36(μ3-OH)30(μ3-O) 6-(bdc)6]54+ ions form a 2D network (see picture), which is further pillared by [Cu3X4(ina) 6]4- to give a 3D framework. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：73 / 77

页数：5

相关论文

共 65 条

[41] Nine-coordinate lanthanide podates with predetermined structural and electronic properties:: Facial organization of unsymmetrical tridentate binding units by a protonated covalent tripod [J].

Renaud, F ;

Piguet, C ;

Bernardinelli, G ;

Bünzli, JCG ;

Hopfgartner, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (40) :9326-9342

[42] Supramolecular assembly of ligand-directed triangular {CuII3Cl} clusters with spin frustration and spin-chain behaviour [J].

Seeber, G ;

Kögerler, P ;

Kariuki, BM ;

Cronin, L .

CHEMICAL COMMUNICATIONS, 2004, (14) :1580-1581

[43] A novel unexpected luminescent quarternary coordination polymer {Sm3(C8H4O4)4(C12N2H8)2(NO3)}n with three high asymmetrical central Sm fragments by hydrothermal assembly [J].

Song, YS ;

Yan, B .

INORGANICA CHIMICA ACTA, 2005, 358 (01) :191-195

[44] Ferrous wheels, ellipse [(tBu3SiS)FeX]n, and cube [(tBu3SiS)Fe(CCSitBu3)]4 [J].

Sydora, OL ;

Wolczanski, PT ;

Lobkovsky, EB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (23) :2685-2687

[45]

SYDORA OL, 2003, ANGEW CHEM, V115, P2789

[46] [FE(OME)(2)(O2CCH2CL)](10), A MOLECULAR FERRIS WHEEL [J].

TAFT, KL ;

DELFS, CD ;

PAPAEFTHYMIOU, GC ;

FONER, S ;

GATTESCHI, D ;

LIPPARD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :823-832

[47]

Tasiopoulos A. J., 2004, ANGEW CHEM, V116, P2169

[48] Giant single-molecule magnets:: A {Mn84} torus and its supramolecular nanotubes [J].

Tasiopoulos, AJ ;

Vinslava, A ;

Wernsdorfer, W ;

Abboud, KA ;

Christou, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (16) :2117-2121

[49] Hydrothermal synthesis and structural studies of novel 2-D lanthanide coordination polymers with phthalic acid [J].

Wan, YH ;

Jin, LP ;

Wang, KZ ;

Zhang, LP ;

Zheng, XJ ;

Lu, SZ .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (11) :1590-1596

[50]

Wang R., 1999, ANGEW CHEM, V111, P1929

← 1 2 3 4 5 6 7 →