Lanthanide-transition-metal sandwich framework comprising {Cu3} cluster pillars and layered networks of {Er36}) wheels

被引：332

作者：

Cheng, JW ^{[1
]}

Zhang, J ^{[1
]}

Zheng, ST ^{[1
]}

Zhang, MB ^{[1
]}

Yang, GY ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 01期

关键词：

bridging ligands; cluster compounds; copper; hydrothermal synthesis; lanthanides;

D O I：

10.1002/anie.200502917

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synergistic coordination between isonicotinate (ina) and 1,2-benzenedicarboxylate (bdc) ligands under hydrothermal conditions results in the formation of two new coordination polymers, [Er7(μ 3-O)(μ3-OH)6(bdc)3](ina) 9[Cu3X4] (X = Cl, Br). Wheel-shaped [Er 36(μ3-OH)30(μ3-O) 6-(bdc)6]54+ ions form a 2D network (see picture), which is further pillared by [Cu3X4(ina) 6]4- to give a 3D framework. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：73 / 77

页数：5

共 65 条

[61]

Xu J., 2000, ANGEW CHEM, V112, P2857

[62] Zinc phosphate with gigantic pores of 24 tetrahedra [J].

Yang, GY ;

Sevov, SC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (36) :8389-8390

[63] A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands [J].

Zhang, MB ;

Zhang, J ;

Zheng, ST ;

Yang, GY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (09) :1385-1388

[64]

ZHANG MB, 2005, ANGEW CHEM, V117, P1409

[65] Ligand-controlled self-assembly of polynuclear lanthanide-oxo/hydroxo complexes: from synthetic serendipity to rational supramolecular design [J].

Zheng, ZP .

CHEMICAL COMMUNICATIONS, 2001, (24) :2521-2529

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