Homopolymer micelles in heterogeneous solvent mixtures

被引:95
作者
Basu, S [1 ]
Vutukuri, DR [1 ]
Thayumanavan, S [1 ]
机构
[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
关键词
D O I
10.1021/ja056042a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amphiphilic homopolymers containing a hydrophilic and a hydrophobic functionality in each monomer unit have been shown to form polar or apolar containers depending on the solvent environment. When presented with a mixture of solvents, these polymeric containers are capable of releasing certain guest molecules. The fundamental mechanism behind these properties is investigated, and the utility of these assemblies in separations has been demonstrated with an example. Copyright © 2005 American Chemical Society.
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页码:16794 / 16795
页数:2
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