Ruthenium catalysts for the Kharasch reaction

被引:138
作者
Severin, K [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland
关键词
D O I
10.2174/138527206775192915
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Recent advances in the development of ruthenium catalysts for the atom transfer radical addition of polyhalogenated compounds to olefins ('Kharasch reaction') are described. Three classes of homogeneous catalysts are discussed: halfsandwich complexes with eta(6)-arene, eta(5)-cyclopentadienyl or eta(5)-carborane ligands, ruthenium complexes with alkylidene- or vinylidene ligands and polynuclear complexes. Furthermore, first attempts to use immobilized ruthenium complexes as heterogeneous catalysts for the Kharasch reaction are summarized.
引用
收藏
页码:217 / 224
页数:8
相关论文
共 66 条