Indenyl- and fluorenyl-functionalized N-heterocyclic carbene complexes of titanium and vanadium

被引：84

作者：

Downing, SP ^{[1
]}

Danopoulos, AA ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 06期

关键词：

D O I：

10.1021/om051017z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new N-heterocyclic carbene ligands functionalized with indenyl and fluorenyl groups, 1-[ind-(CH2)(2)]-NHC, (Ind-NHC)(-), and 1-[fl-(CH2)(2)]-NHC, (Fl-NHC)(-), where ind = 1-indenyl, fl = 9-fluorenyl, NHC = 3-DiPP-imidazol-2-ylidene, DiPP = 2,6-Pr-2(i)-C6H3, serve as versatile building blocks of Ti(III) and V(III) complexes.

引用

页码：1337 / 1340

页数：4

共 51 条

[1] Reactions of transition-metal metallocenes with stable carbenes [J].

Abernethy, CD ;

Clyburne, JAC ;

Cowley, AH ;

Jones, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (10) :2329-2330

[2] Reaction of nickelocene with 1,3-dimesitylimidazolium chloride [J].

Abernethy, CD ;

Cowley, AH ;

Jones, RA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 596 (1-2) :3-5

[3] Nucleophilic carbene complexes of manganocene [J].

Abernethy, CD ;

Cowley, AH ;

Jones, RA ;

Macdonald, CLB ;

Shukla, P ;

Thompson, LK .

ORGANOMETALLICS, 2001, 20 (17) :3629-3631

[4] Titanium N-heterocyclic carbene complexes incorporating an imidazolium-linked bis(phenol) [J].

Aihara, H ;

Matsuo, T ;

Kawaguchi, H .

CHEMICAL COMMUNICATIONS, 2003, (17) :2204-2205

[5] STABLE CARBENES AS STRONG BASES [J].

ALDER, RW ;

ALLEN, PR ;

WILLIAMS, SJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (12) :1267-1268

[6] CARBENE-LANTHANIDE COMPLEXES [J].

ARDUENGO, AJ ;

TAMM, M ;

MCLAIN, SJ ;

CALABRESE, JC ;

DAVIDSON, F ;

MARSHALL, WJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) :7927-7928

[7] Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes [J].

Arnold, PL ;

Rodden, M ;

Wilson, C .

CHEMICAL COMMUNICATIONS, 2005, (13) :1743-1745

[8] New ruthenium(II) complexes bearing N-heterocyclic carbenes [J].

Baratta, W ;

Herdtweck, E ;

Herrmann, WA ;

Rigo, P ;

Schwarz, JD .

ORGANOMETALLICS, 2002, 21 (10) :2101-2106

[9]

Baudry-Barbier D, 1998, EUR J INORG CHEM, P1721

[10] Stable carbenes [J].

Bourissou, D ;

Guerret, O ;

Gabbaï, FP ;

Bertrand, G .

CHEMICAL REVIEWS, 2000, 100 (01) :39-91

← 1 2 3 4 5 6 →