Novel silicon-nickel cone arrays for high performance LIB anodes

被引:26
作者
Fan, Yu [1 ]
Huang, Kai [2 ]
Zhang, Qing [1 ]
Xiao, Qizhen [1 ]
Wang, Xinghui [1 ]
Chen, Xiaodong [3 ]
机构
[1] Nanyang Technol Univ, NOVITAS, Nanoelect Ctr Excellence, Sch Elect & Elect Engn, Singapore 639798, Singapore
[2] Xiangtan Univ, Key Lab Quantum Engn & Micronano Energy Technol, Sch Mat Optoelect & Phys, Xiangtan 411105, Peoples R China
[3] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
关键词
LITHIUM-ION BATTERIES; THIN-FILM ELECTRODES; AMORPHOUS SI; DEPOSITION; MICROSTRUCTURE; NANOWIRES;
D O I
10.1039/c2jm34337a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report on a high performance silicon anode based on silicon-nickel cone arrays. The composite electrode exhibits good capacity retention and remarkable rate performance. A de-lithiation capacity of 2639, 2341, 2042, 1806, 1693, 1523 and 1308 mA h g(-1) is retained at 0.2, 0.5, 1, 2, 3, 4 and 5 C, respectively.
引用
收藏
页码:20870 / 20873
页数:4
相关论文
共 26 条
[11]   Highly Interconnected Si Nanowires for Improved Stability Li-Ion Battery Anodes [J].
Nguyen, Hung T. ;
Yao, Fei ;
Zamfir, Mihai R. ;
Biswas, Chandan ;
So, Kang Pyo ;
Lee, Young Hee ;
Kim, Seong Min ;
Cha, Seung Nam ;
Kim, Jong Min ;
Pribat, Didier .
ADVANCED ENERGY MATERIALS, 2011, 1 (06) :1154-1161
[12]   Reversible cycling of crystalline silicon powder [J].
Obrovac, M. N. ;
Krause, L. J. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (02) :A103-A108
[13]   Cobalt Nanoparticle Arrays made by Templated Solid-State Dewetting [J].
Oh, Yong-Jun ;
Ross, Caroline A. ;
Jung, Yeon Sik ;
Wang, Yang ;
Thompson, Carl V. .
SMALL, 2009, 5 (07) :860-865
[14]   Silicon Nanotube Battery Anodes [J].
Park, Mi-Hee ;
Kim, Min Gyu ;
Joo, Jaebum ;
Kim, Kitae ;
Kim, Jeyoung ;
Ahn, Soonho ;
Cui, Yi ;
Cho, Jaephil .
NANO LETTERS, 2009, 9 (11) :3844-3847
[15]   Towards a fundamental understanding of the improved electrochemical performance of silicon-carbon composites [J].
Saint, Juliette ;
Morcrette, Mathieu ;
Larcher, Dominique ;
Laffont, Lydia ;
Beattie, Shane ;
Peres, Jean-Paul ;
Talaga, David ;
Couzi, Michel ;
Tarascon, Jean-Marie .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (11) :1765-1774
[16]   In situ Raman scattering studies of the amorphous and crystalline Si nanoparticles [J].
Sirenko, AA ;
Fox, JR ;
Akimov, IA ;
Xi, XX ;
Ruvimov, S ;
Liliental-Weber, Z .
SOLID STATE COMMUNICATIONS, 2000, 113 (10) :553-558
[17]   Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries [J].
Song, Taeseup ;
Xia, Jianliang ;
Lee, Jin-Hyon ;
Lee, Dong Hyun ;
Kwon, Moon-Seok ;
Choi, Jae-Man ;
Wu, Jian ;
Doo, Seok Kwang ;
Chang, Hyuk ;
Park, Won Il ;
Zang, Dong Sik ;
Kim, Hansu ;
Huang, Yonggang ;
Hwang, Keh-Chih ;
Rogers, John A. ;
Paik, Ungyu .
NANO LETTERS, 2010, 10 (05) :1710-1716
[18]   Li ion battery materials with core-shell nanostructures [J].
Su, Liwei ;
Jing, Yu ;
Zhou, Zhen .
NANOSCALE, 2011, 3 (10) :3967-3983
[19]   Core double-shell Si@SiO2@C nanocomposites as anode materials for Li-ion batteries [J].
Su, Liwei ;
Zhou, Zhen ;
Ren, Manman .
CHEMICAL COMMUNICATIONS, 2010, 46 (15) :2590-2592
[20]   Silicon-based composite anodes for Li-ion rechargeable batteries [J].
Wang, Wei ;
Datta, Moni Kanchan ;
Kumta, Prashant N. .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3229-3237