Microtopographic and molecular scale observations of zeolite surface structures: Atomic force microscopy on natural heulandite

被引:26
作者
Binder, G [1 ]
Scandella, L [1 ]
Schumacher, A [1 ]
Kruse, N [1 ]
Prins, R [1 ]
机构
[1] TECH CHEM LAB,ZURICH,SWITZERLAND
来源
ZEOLITES | 1996年 / 16卷 / 01期
关键词
atomic force microscopy; heulandite;
D O I
10.1016/0144-2449(95)00085-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Atomic force microscopy (AFM) has been employed to study the surface of the natural zeolite heulandite. Images on a macroscopic scale exhibit growth spirals on the outer surface and cleavage tips an the (010) surface, both with terraces separated from each other by half of the unit cell length b. The angle of the cleavage tips depends on the cleaving direction. Molecular resolution is obtained when measured in 0.1 M NaOH, 0.1 and 1 M KOH, and 6.66 M CsOH. The influence of immersion time, the nature of the ion species, and the ion concentration on the unit cell has been investigated. The lattice constants varied around the bulk values.
引用
收藏
页码:2 / 6
页数:5
相关论文
共 28 条
[11]   SCANNING TUNNELING MICROSCOPY AND ATOMIC FORCE MICROSCOPY IN ORGANIC-CHEMISTRY [J].
FROMMER, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (10) :1298-1328
[12]  
GOTTARDI G, 1985, NATURAL ZEOLITES, P40
[13]  
GUTMANNSBAUER W, 1995, SCHWEIZ MINER PETROG, V75, P259
[14]   SCANNING NEAR-FIELD OPTICAL MICROSCOPY [J].
HEINZELMANN, H ;
POHL, DW .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1994, 59 (02) :89-101
[15]   STM IMAGE OF SILICATE-1 PORE STRUCTURE [J].
JANSEN, JC ;
SCHOONMAN, J ;
VANBEKKUM, H ;
PINET, V .
ZEOLITES, 1991, 11 (04) :306-307
[16]   ATOMIC-FORCE MICROSCOPY IMAGES OF NATURAL ZEOLITE SURFACES OBSERVED UNDER AMBIENT CONDITIONS [J].
KOMIYAMA, M ;
YASHIMA, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1994, 33 (6B) :3761-3763
[17]   MOLECULAR RESOLUTION OF ZEOLITE SURFACES AS IMAGED BY ATOMIC FORCE MICROSCOPY [J].
MACDOUGALL, JE ;
COX, SD ;
STUCKY, GD ;
WEISENHORN, AL ;
HANSMA, PK ;
WISE, WS .
ZEOLITES, 1991, 11 (05) :429-433
[18]   ATOMIC FORCE MICROSCOPY [J].
MEYER, E .
PROGRESS IN SURFACE SCIENCE, 1992, 41 (01) :3-49
[19]  
OCCELLI ML, 1994, STUD SURF SCI CATAL, V84, P485
[20]   THERMODYNAMICS OF ION-EXCHANGE BETWEEN CLINOPTILOLITE AND AQUEOUS-SOLUTIONS OF NA+/K+ AND NA+/CA2+ [J].
PABALAN, RT .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1994, 58 (21) :4573-4590