Ten years of axial capacitively coupled contactless conductivity detection for CZE - a review

被引:192
作者
Kuban, Pavel [2 ]
Hauser, Peter C. [1 ]
机构
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
[2] Acad Sci Czech Republ, Inst Analyt Chem, CS-61142 Brno, Czech Republic
关键词
Capacitively coupled contactless conductivity detection; CE; Microchip electrophoresis; Review; CAPILLARY-ZONE-ELECTROPHORESIS; PERFORMANCE LIQUID-CHROMATOGRAPHY; UNDERIVATIZED AMINO-ACIDS; WEIGHT ORGANIC-ACIDS; CONDUCTOMETRIC DETECTOR; FLOW INJECTION; MICROCHIP ELECTROPHORESIS; INORGANIC-IONS; ENANTIOMERIC SEPARATION; OSCILLOMETRIC DETECTOR;
D O I
10.1002/elps.200800478
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Contactless conductivity detection is universal for CE in that all charged species can be quantified, and it is particularly attractive for those inorganic and organic ions that are not directly accessible by optical means. It is not necessary to make precise alignments or to create an optical window into the capillary. Commercial detectors that can be retrofitted to existing instruments are available at a cost that is lower than that of any other electrophoresis detector. The approach is also suited for lab-on-chip devices. It is attempted in this review to summarize some of the expertise accumulated since the introduction of the axial contactless conductivity detector to CE 10 years ago.
引用
收藏
页码:176 / 188
页数:13
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