Synthesis of platinum(II) cyclometallated compounds derived from imines containing pyridyl or pyrimidyl groups

被引：11

作者：

Crespo, Margarita ^{[1
]}

Anderson, Craig M. ^{[2
]}

Tanski, Joseph M. ^{[3
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[2] Bard Coll, Dept Chem, Annandale on Hudson, NY 12504 USA

[3] Vassar Coll, Dept Chem, Poughkeepsie, NY 12604 USA

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2009年 / 87卷 / 01期

基金：

美国国家科学基金会;

关键词：

platinum; imines; pyridyl; pyrimidyl; cyclometallation; crystal structure; TRANSITION-METAL-COMPLEXES; UNACTIVATED METHYL-GROUPS; 5-MEMBERED RING COMPOUNDS; ARYL HALOGEN BONDS; C-H BONDS; CRYSTAL-STRUCTURES; N-BENZYLIDENEBENZYLAMINES; OXIDATIVE ADDITION; ORGANIC-SYNTHESIS; ACTIVATION;

D O I：

10.1139/V08-084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of compounds [Pt2Me4(mu-SMe2)(2)] and cis-[PtPh2(SMe2)(2)] with ligands 4-(2'-C5H4N)C6H4CHNCH2CH2NMe2 (1a) and 4-(3',5'-C4H3N2)C6H4CHNCH2CH2NMe2 (1b) carried out in acetone at room temperature produced compounds in which the imines act as bidentate [N,N'] ligands. Analogous compounds could be obtained in refluxing methanol when cis-[PtCl2(DMSO)(2)] was used as starting material. The corresponding cyclometallation processes leading to platinum(II) compounds with a tridentate [C, N, N'] ligand took place under different reaction conditions, except for metallation of 1a with cis-[PtPh2(SMe2)(2)], which could not be achieved. All compounds were characterized by usual techniques and [PtMe{4-(3',5'-C4H3N2)C6H3CHNCH2CH2NMe2}] (3bMe) was also characterized crystallographically.

引用

页码：80 / 87

页数：8

共 39 条

[31] MECHANISMS OF INTRAMOLECULAR ACTIVATION OF C-H BONDS IN TRANSITION-METAL COMPLEXES [J].