A stable hydrido amido ruthenium complex bearing a tridentate iminophosphorane-phosphine-amine ligand

被引：41

作者：

Boubekeur, L ^{[1
]}

Ulmer, S ^{[1
]}

Ricard, L ^{[1
]}

Mézailles, N ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] CNRS, UMR 7653, Dept Chim, Lab Heteroelements & Coordinat,Ecole Polytech, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 02期

关键词：

D O I：

10.1021/om050738v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A heterotridentate (P,N,N') ligand featuring phosphine, iminophosphorane, and amine groups has been prepared in high yield. The corresponding dichlororuthenium(II) complex reacts with base in 2-propanol to give a stable hydrido amido complex. The lack of hydrogens that are a to the amine allowed for the isolation and structural. characterization of this hydrido amido species by X-ray diffraction.

引用

页码：315 / 317

页数：3

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