Influence of a dimetal ion binding ferrocene ligand on the samarium diiodide promoted pinacol coupling reaction

被引：23

作者：

Christensen, TB ^{[1
]}

Riber, D ^{[1
]}

Daasbjerg, K ^{[1
]}

Skrydstrup, T ^{[1
]}

机构：

[1] Univ Aarhus, Dept Chem, DK-8000 Aarhus C, Denmark

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 20期

关键词：

D O I：

10.1039/a904278d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Substantial yield increases have been noted in the use of a di-SmI2 binding ligand for the pinacol coupling of alkyl aldehydes compared to 1:1 complexes of SmI2 and tetraglyme. High diastereoselectivities of ca. 10:1 are also observed for alpha-substituted alkyl aldehydes in favour of the (+/-)-isomers.

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页码：2051 / 2052

页数：2

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