Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state

被引：57

作者：

Blas-Ferrando, Vicente M. ^{[2
]}

Ortiz, Javier ^{[2
]}

Bouissane, Latifa ^{[2
]}

Ohkubo, Kei ^{[1
]}

Fukuzumi, Shunichi ^{[1
,3
]}

Fernandez-Lazaro, Fernando ^{[2
]}

Sastre-Santos, Angela ^{[2
]}

机构：

[1] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, ALCA,Japan Sci & Technol Agcy JST, Suita, Osaka 5650871, Japan

[2] Univ Miguel Hernandez, Div Quim Organ, Inst Bioingn, Elche 03202, Spain

[3] Ewha Womans Univ, Dept Bioinspired Sci, Seoul 120750, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 50期

关键词：

PHOTOINDUCED ELECTRON-TRANSFER; ION PAIR STATES; MAGNESIUM-ION; SOLAR-CELLS; DYES; SYSTEMS; COMPLEXATION; MOLECULES; ENERGY; TRIAD;

D O I：

10.1039/c2cc31087b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new ZnPc-PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 mu s.

引用

页码：6241 / 6243

页数：3

共 45 条

[1] Single Layer of Polymeric Fe-Phthalocyanine: An Organometallic Sheet on Metal and Thin Insulating Film [J].

Abel, Mathieu ;

Clair, Sylvain ;

Ourdjini, Oualid ;

Mossoyan, Mireille ;

Porte, Louis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1203-1205

[2] Multichromophoric Phthalocyanine-(Perylenediimide)8 Molecules: A Photophysical Study [J].

Albert-Seifried, Sebastian ;

Finlayson, Chris E. ;

Laquai, Frederic ;

Friend, Richard H. ;

Swager, Timothy M. ;

Kouwer, Paul H. J. ;

Juricek, Michal ;

Kitto, Heather J. ;

Valster, Sanne ;

Nolte, Roeland J. M. ;

Rowan, Alan E. .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (33) :10021-10029

[3] Energetic factors governing injection, regeneration and recombination in dye solar cells with phthalocyanine sensitizers [J].

Barea, Eva M. ;

Ortiz, Javier ;

Paya, Federico J. ;

Fernandez-Lazaro, Fernando ;

Fabregat-Santiago, Francisco ;

Sastre-Santos, Angela ;

Bisquert, Juan .

ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (12) :1985-1994

[4] Efficient electroluminescence from a perylenediimide fluorophore obtained from a simple solution processed OLED [J].

Cespedes-Guirao, F. J. ;

Garcia-Santamaria, S. ;

Fernandez-Lazaro, F. ;

Sastre-Santos, A. ;

Bolink, H. J. .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2009, 42 (10)

[5] A water-soluble perylene dye functionalised with a 17β-estradiol: a new fluorescent tool for steroid hormones [J].

Cespedes-Guirao, Francisco J. ;

Ropero, Ana B. ;

Font-Sanchis, Enrique ;

Nadal, Angel ;

Fernandez-Lazaro, Fernando ;

Sastre-Santos, Angela .

CHEMICAL COMMUNICATIONS, 2011, 47 (29) :8307-8309

[6] Supramolecular zinc phthalocyanine-perylene bisimide triad: Synthesis and photophysical properties [J].

Chen, Yu ;

Lin, Ying ;

El-Khouly, Mohamed E. ;

Zhuang, Xiaodong ;

Araki, Yasuyuki ;

Ito, Osamu ;

Zhang, Weian .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (44) :16096-16099

[7] Efficient deep-red light-emitting electrochemical cells based on a perylenediimide-iridium-complex dyad [J].

Costa, Ruben D. ;

Cespedes-Guirao, Francisco J. ;

Orti, Enrique ;

Bolink, Henk J. ;

Gierschner, Johannes ;

Fernandez-Lazaro, Fernando ;

Sastre-Santos, Angela .

CHEMICAL COMMUNICATIONS, 2009, (26) :3886-3888

[8] Role of structural factors in the nonlinear optical properties of phthalocyanines and related compounds [J].

de la Torre, G ;

Váquez, P ;

Agulló-López, F ;

Torres, T .

CHEMICAL REVIEWS, 2004, 104 (09) :3723-3750

[9] Phthalocyanines: old dyes, new materials. Putting color in nanotechnology [J].

de la Torre, Gema ;

Claessens, Christian G. ;

Torres, Tomas .

CHEMICAL COMMUNICATIONS, 2007, (20) :2000-2015

[10] Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion [J].

Fukuzumi, S ;

Ohkubo, K ;

Ortiz, J ;

Gutiérrez, AM ;

Fernández-Lázaro, F ;

Sastre-Santos, A .

CHEMICAL COMMUNICATIONS, 2005, (30) :3814-3816

← 1 2 3 4 5 →