Iodine-templated assembly of unprecedented 3d-4f metal-organic frameworks as photocatalysts for hydrogen generation

被引：98

作者：

Hu, Xiao-Li ^{[1
]}

Sun, Chun-Yi ^{[1
]}

Qin, Chao ^{[1
]}

Wang, Xin-Long ^{[1
]}

Wang, Hai-Ning ^{[1
]}

Zhou, En-Long ^{[1
]}

Li, Wen-E ^{[1
]}

Su, Zhong-Min ^{[1
]}

机构：

[1] NE Normal Univ, Inst Funct Mat Chem, Key Lab Polyoxometalate Sci, Minist Educ, Changchun 130024, Jilin, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 34期

关键词：

SINGLE-CRYSTAL; ELECTROCHEMICAL PROPERTIES; ELECTRICAL-CONDUCTIVITY; COORDINATION POLYMERS; 3D FRAMEWORK; CLUSTERS; RELEASE; COMPLEXES; CHEMISTRY; MAGNETS;

D O I：

10.1039/c3cc39173f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unprecedented 3d-4f MOFs encapsulating infinite linear polyiodide chains were firstly reported using iodine molecules as a versatile precursor template. They possess high framework stability in acid/base aqueous solutions. The kinetics of iodine molecule release/recovery and UV-light photocatalytic H-2 evolution activities were investigated.

引用

页码：3564 / 3566

页数：3

共 33 条

[1] Hydrothermal synthesis of divalent metal pyromellitate/dipyridylamine complexes: From an unprecedented supramolecular three-dimensional topology to an anionic coordination polymer framework with large incipient cation-bearing voids [J].

Braverman, Maxwell A. ;

LaDuca, Robert L. .

CRYSTENGCOMM, 2008, 10 (01) :117-124

[2] Unusual microporous polycatenane-like metal-organic frameworks for the luminescent sensing of Ln3+ cations and rapid adsorption of iodine [J].

Chen, Lei ;

Tan, Ke ;

Lan, Ya-Qian ;

Li, Shun-Li ;

Shao, Kui-Zhan ;

Su, Zhong-Min .

CHEMICAL COMMUNICATIONS, 2012, 48 (47) :5919-5921

[3] Alkali-Metal-Templated Assemblies of New 3D Lead(II) Tetrachloroterephthalate Coordination Frameworks [J].

Chen, Sheng-Chun ;

Zhang, Zhi-Hui ;

Zhou, Yong-Sheng ;

Zhou, Wei-You ;

Li, Yi-Zhi ;

He, Ming-Yang ;

Chen, Qun ;

Du, Miao .

CRYSTAL GROWTH & DESIGN, 2011, 11 (09) :4190-4197

[4] Dynamic and redox active pillared bilayer open framework: Single-crystal-to-single-crystal transformations upon guest removal, guest exchange, and framework oxidation [J].

Choi, HJ ;

Suh, MP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (48) :15844-15851

[5] Strategy for the Rational Design of Asymmetric Triply Bridged Dinuclear 3d-4f Single-Molecule Magnets [J].

Colacio, Enrique ;

Ruiz-Sanchez, Jose ;

White, Fraser J. ;

Brechin, Euan K. .

INORGANIC CHEMISTRY, 2011, 50 (15) :7268-7273

[6] First 3D Pr(III)-Ni(II)-Na(I) polymer and a 3D Pr(III) open network based on pyridine-2,4,6-tricarboxylic acid [J].

Gao, HL ;

Yi, L ;

Ding, B ;

Wang, HS ;

Cheng, P ;

Liao, DZ ;

Yan, SP .

INORGANIC CHEMISTRY, 2006, 45 (02) :481-483

[7] Molecular Doping of Porous Organic Cages [J].

Hasell, Tom ;

Schmidtmann, Marc ;

Cooper, Andrew I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (38) :14920-14923

[8] Controllable synthesis of a non-interpenetrating microporous metal-organic framework based on octahedral cage-like building units for highly efficient reversible adsorption of iodine [J].

He, Wen-Wen ;

Li, Shun-Li ;

Yang, Guang-Sheng ;

Lan, Ya-Qian ;

Su, Zhong-Min ;

Fu, Qiang .

CHEMICAL COMMUNICATIONS, 2012, 48 (80) :10001-10003

[9] Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release [J].

He, Yuan-Chun ;

Yang, Jin ;

Yang, Guo-Cheng ;

Kan, Wei-Qiu ;

Ma, Jian-Fang .

CHEMICAL COMMUNICATIONS, 2012, 48 (63) :7859-7861

[10] Self-Assembly and Photocatalytic Properties of Polyoxoniobates: {Nb24O72}, {Nb32O96}, and {K12Nb96O288} Clusters [J].

Huang, Peng ;

Qin, Chao ;

Su, Zhong-Min ;

Xing, Yan ;

Wang, Xin-Long ;

Shao, Kui-Zhan ;

Lan, Ya-Qian ;

Wang, En-Bo .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (34) :14004-14010

← 1 2 3 4 →