Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release

被引：76

作者：

He, Yuan-Chun ^{[1
]}

Yang, Jin ^{[1
]}

Yang, Guo-Cheng ^{[2
]}

Kan, Wei-Qiu ^{[1
]}

Ma, Jian-Fang ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

[2] Changchun Univ Technol, Sch Chem & Life Sci, Changchun 130012, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 63期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; COORDINATION POLYMER; STRUCTURAL TRANSFORMATIONS; ANION-EXCHANGE; PHOTODIMERIZATION; NETWORK; PHOTOCHROMISM; CONDUCTIVITY; CHEMISTRY; MECHANISM;

D O I：

10.1039/c2cc33831a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe an exceedingly rare example of solid-state single-crystal-to-single-crystal transformation from a 2D layer to a known 3D framework via lattice iodine release, which involves the formation of a new Cu-O ligand bond and a change in the metal coordination geometry.

引用

页码：7859 / 7861

页数：3

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