Reversible topochemical transformation of a soft crystal of a coordination polymer

被引：205

作者：

Ghosh, Sujit K. ^{[1
]}

Zhang, Jie-Peng ^{[1
]}

Kitagawa, Susumu ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 42期

关键词：

adsorption; coordination polymers; phase transitions; solid-state structures; structure elucidation;

D O I：

10.1002/anie.200703086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Shaping up: The two isomorphous 2D hybrid frameworks {[Ln(tci)-(H2O)2]·2H2O}n (Ln = CeIII or PrIII, tciH3 = tris(2-carboxyethyl) isocyanurate) were prepared using a highly flexible ligand. The frameworks show a single crystal to single crystal topochemical transformation from a two-dimensional (2D) to three-dimensional (3D) framework and vice versa (see picture) and exhibits selective adsorption properties of H2O over MeOH and EtOH. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7965 / 7968

页数：4

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