Molecular Doping of Porous Organic Cages

被引：211

作者：

Hasell, Tom

Schmidtmann, Marc

Cooper, Andrew I. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 38期

基金：

英国工程与自然科学研究理事会;

关键词：

OSMIUM-TETROXIDE; SINGLE-CRYSTAL; FRAMEWORK; POLYMERS; DESIGN; IODINE; POLYIODIDE; CHEMISTRY; FIXATION; CHANNELS;

D O I：

10.1021/ja205969q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porous organic cages can act as hosts for the three-dimensional alignment of guests such as halogens and organometallics. Porous single crystals are doped by vapor sublimation to produce diamondoid arrangements of guests such as I-5(-) and OsO4, leading to marked conductivity enhancement in the case of I-5(-).

引用

收藏

页码：14920 / 14923

页数：4

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