共 268 条
Post-Functionalization of Polymers via Orthogonal Ligation Chemistry
被引:177
作者:
Goldmann, Anja S.
[1
]
Glassner, Mathias
[1
]
Inglis, Andrew J.
[1
]
Barner-Kowollik, Christopher
[1
]
机构:
[1] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, D-76131 Karlsruhe, Germany
关键词:
click chemistry;
modular and orthogonal ligation;
post-functionalization;
polymers;
DIELS-ALDER REACTION;
OPENING METATHESIS POLYMERIZATION;
TRANSFER RADICAL POLYMERIZATION;
FREE CLICK CHEMISTRY;
AZIDE-ALKYNE CYCLOADDITION;
PALLADIUM-CATALYZED VINYLATION;
CHAIN TRANSFER POLYMERIZATION;
PHASE-TRANSFER CONDITIONS;
DEFINED BLOCK-COPOLYMERS;
ABC TRIBLOCK COPOLYMERS;
D O I:
10.1002/marc.201300017
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
The establishment of advanced living/controlled polymerization protocols allows for engineering synthetic polymers in a precise fashion. Combining advanced living/controlled polymerization techniques with highly efficient coupling chemistries facilitates quantitative, modular, and orthogonal functionalization of synthetic polymer strands at their chain termini as well as side-chain functionalization. The review highlights the current status of selected post-functionalization techniques of polymers via orthogonal ligation chemistries, major characteristics of the specific transformation chemistry, as well as the characterization of the products.
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页码:810 / 849
页数:40
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