Colloidal Crystal-Derived Nanoporous Electrode Materials of Cut SWNTs-Assembly and TiO2/SWNTs Nanocomposite

被引:25
作者
Moriguchi, Isamu [1 ]
Shono, Yuki [2 ]
Yamada, Hirotoshi [1 ]
Kudo, Tetsuichi [3 ]
机构
[1] Nagasaki Univ, Fac Engn, Nagasaki 8528521, Japan
[2] Nagasaki Univ, Grad Sch Sci & Technol, Nagasaki 8528521, Japan
[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058568, Japan
关键词
D O I
10.1021/jp802649t
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Relatively ordered macroporous films of a cut single-walled carbon nanotubes (c-SWNTs) assembly and a TiO2/c-SWNTs nanocomposite were successfully fabricated by colloidal crystal template processes using polystyrene particles. The macroporous TiO2/c-SWNTs nanocomposite film showed excellent rate capability of Li-insertion/extraction. The rate-dependent Li-insertion/extraction capacities were close to theoretical values expected from Li-diffusion in anatase-TiO2 thin layer without blocking electrolyte-ion and electron access.
引用
收藏
页码:14560 / 14565
页数:6
相关论文
共 27 条
[1]  
Cassagneau T, 2002, ADV MATER, V14, P34, DOI 10.1002/1521-4095(20020104)14:1<34::AID-ADMA34>3.0.CO
[2]  
2-M
[3]   Synthesis and characterization of SnO-carbon nanotube composite as anode material for lithium-ion batteries [J].
Chen, MH ;
Huang, ZC ;
Wu, GT ;
Zhu, GM ;
You, JK ;
Lin, ZG .
MATERIALS RESEARCH BULLETIN, 2003, 38 (05) :831-836
[4]   Purification and characterization of single-wall carbon nanotubes (SWNTs) obtained from the gas-phase decomposition of CO (HiPco process) [J].
Chiang, IW ;
Brinson, BE ;
Huang, AY ;
Willis, PA ;
Bronikowski, MJ ;
Margrave, JL ;
Smalley, RE ;
Hauge, RH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (35) :8297-8301
[5]   Synthesis and characterization of carbon nanotubes -: TiO2 nanocomposites [J].
Jitianu, A ;
Cacciaguerra, T ;
Benoit, R ;
Delpeux, S ;
Béguin, F ;
Bonnamy, S .
CARBON, 2004, 42 (5-6) :1147-1151
[6]   DIFFUSION OF LITHIUM IN THE TIO2 CATHODE OF A LITHIUM BATTERY [J].
KANAMURA, K ;
YUASA, K ;
TAKEHARA, Z .
JOURNAL OF POWER SOURCES, 1987, 20 (1-2) :127-134
[7]   Lithium insertion into anatase inverse opal [J].
Kavan, L ;
Zukalová, MT ;
Kalbác, M ;
Graetzel, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (08) :A1301-A1307
[8]   Surfactant-templated TiO2 (anatase):: Characteristic features of lithium insertion electrochemistry in organized nanostructures [J].
Kavan, L ;
Rathousky, J ;
Grätzel, M ;
Shklover, V ;
Zukal, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (50) :12012-12020
[9]   Amorphous V2O5/carbon composites as electrochemical supercapacitor electrodes [J].
Kudo, T ;
Ikeda, Y ;
Watanabe, T ;
Hibino, M ;
Miyayama, M ;
Abe, H ;
Kajita, K .
SOLID STATE IONICS, 2002, 152 :833-841
[10]   Li+ ion insertion in TiO2 (anatase) .2. Voltammetry on nanoporous films [J].
Lindstrom, H ;
Sodergren, S ;
Solbrand, A ;
Rensmo, H ;
Hjelm, J ;
Hagfeldt, A ;
Lindquist, SE .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (39) :7717-7722