Colloidal Crystal-Derived Nanoporous Electrode Materials of Cut SWNTs-Assembly and TiO2/SWNTs Nanocomposite

被引:25
作者
Moriguchi, Isamu [1 ]
Shono, Yuki [2 ]
Yamada, Hirotoshi [1 ]
Kudo, Tetsuichi [3 ]
机构
[1] Nagasaki Univ, Fac Engn, Nagasaki 8528521, Japan
[2] Nagasaki Univ, Grad Sch Sci & Technol, Nagasaki 8528521, Japan
[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058568, Japan
关键词
D O I
10.1021/jp802649t
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Relatively ordered macroporous films of a cut single-walled carbon nanotubes (c-SWNTs) assembly and a TiO2/c-SWNTs nanocomposite were successfully fabricated by colloidal crystal template processes using polystyrene particles. The macroporous TiO2/c-SWNTs nanocomposite film showed excellent rate capability of Li-insertion/extraction. The rate-dependent Li-insertion/extraction capacities were close to theoretical values expected from Li-diffusion in anatase-TiO2 thin layer without blocking electrolyte-ion and electron access.
引用
收藏
页码:14560 / 14565
页数:6
相关论文
共 27 条
[21]   Single-walled carbon nanotubes coated with titania nanoparticles [J].
Sun, J ;
Iwasa, M ;
Gao, L ;
Zhang, QH .
CARBON, 2004, 42 (04) :895-899
[22]   In situ X-ray diffraction of lithium intercalation in nanostructured and thin film anatase TiO2 [J].
van de Krol, R ;
Goossens, A ;
Meulenkamp, EA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (09) :3150-3154
[23]   Interconnected macroporous TiO2 (anatase) as a lithium insertion electrode material [J].
Yamada, H ;
Yamato, T ;
Moriguchi, I ;
Kudo, T .
SOLID STATE IONICS, 2004, 175 (1-4) :195-198
[24]   Porous TiO2 (anatase) electrodes for high-power batteries [J].
Yamada, H ;
Yamato, T ;
Moriguchi, I ;
Kudo, T .
CHEMISTRY LETTERS, 2004, 33 (12) :1548-1549
[25]   High power battery electrodes using nanoporous V2O5/carbon composites [J].
Yamada, Hirotoshi ;
Tagawa, Kazuki ;
Komatsu, Masaharu ;
Moriguchi, Isamu ;
Kudo, Tetsuichi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (23) :8397-8402
[26]   Electrochemical study of high electrochemical double layer capacitance of ordered porous carbons with both meso/macropores and micropores [J].
Yamada, Hirotoshi ;
Nakamura, Haruka ;
Nakahara, Fumihiro ;
Moriguchi, Isamu ;
Kudo, Tetsuichi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (01) :227-233
[27]   A self-ordered, crystalline-glass, mesoporous nanocomposite for use as a lithium-based storage device with both high power and high energy densities [J].
Zhou, HS ;
Li, DL ;
Hibino, M ;
Honma, I .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (05) :797-802