Low-voltage high-performance C60 thin film transistors via low-surface-energy phosphonic acid monolayer/hafnium oxide hybrid dielectric

被引:26
作者
Acton, Orb [1 ]
Ting, Guy [2 ]
Ma, Hong [1 ,3 ]
Jen, Alex K. -Y. [1 ,2 ,3 ]
机构
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
[3] Univ Washington, Inst Adv Mat & Technol, Seattle, WA 98195 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2975175
中图分类号
O59 [应用物理学];
学科分类号
摘要
C(60)-based organic thin film transistors (OTFTs) have been fabricated using a n-octadecylphosphonic acid self-assembled monolayer/ sol-gel processed hafnium oxide hybrid dielectric. With the combination of high capacitance (580 nF/cm(2)) and low leakage current density (8 x 10(-9) A/cm(2)), this hybrid dielectric yields C(60) OTFTs operating under 1.5 V with an average n-channel saturation field-effect mobility of 0.28 cm(2)/V s, high on-off current ratio of 105, and low subthreshold slope of 100 mV/decade. The low surface energy of the n-octadecylphosphonic acid allows C(60) to form a thin film with large grains that provide an efficient charge carrier pathway for the low-voltage OTFTs. (c) 2008 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 22 条
[1]  
ACTON O, ADV MAT WEI IN PRESS, P44505
[2]   Optimization of precursor pulse time in improving bulk trapping characteristics of atomic-layer-deposition HfO2 gate oxides [J].
Akbar, MS ;
Lee, JC ;
Moumen, N ;
Peterson, J .
APPLIED PHYSICS LETTERS, 2006, 88 (08)
[3]   Suppression of charge carrier tunneling through organic self-assembled monolayers [J].
Boulas, C ;
Davidovits, JV ;
Rondelez, F ;
Vuillaume, D .
PHYSICAL REVIEW LETTERS, 1996, 76 (25) :4797-4800
[4]   Organic single-crystal complementary inverter [J].
Briseno, Alejandro L. ;
Tseng, Ricky J. ;
Li, Sheng-Han ;
Chu, Chih-Wei ;
Yang, Yang ;
Falcao, Eduardo H. L. ;
Wudl, Fred ;
Ling, Mang-Mang ;
Chen, Hong Zheng ;
Bao, Zhenan ;
Meng, Hong ;
Kloc, Christian .
APPLIED PHYSICS LETTERS, 2006, 89 (22)
[5]   General observation of n-type field-effect behaviour in organic semiconductors [J].
Chua, LL ;
Zaumseil, J ;
Chang, JF ;
Ou, ECW ;
Ho, PKH ;
Sirringhaus, H ;
Friend, RH .
NATURE, 2005, 434 (7030) :194-199
[6]   Low-voltage, 30 nm channel length, organic transistors with a self-assembled monolayer as gate insulating films [J].
Collet, J ;
Tharaud, O ;
Chapoton, A ;
Vuillaume, D .
APPLIED PHYSICS LETTERS, 2000, 76 (14) :1941-1943
[7]   Gate dielectrics for organic field-effect transistors: New opportunities for organic electronics [J].
Facchetti, A ;
Yoon, MH ;
Marks, TJ .
ADVANCED MATERIALS, 2005, 17 (14) :1705-1725
[8]   SELF-ASSEMBLED MONOLAYERS OF LONG-CHAIN HYDROXAMIC ACIDS ON THE NATIVE OXIDES OF METALS [J].
FOLKERS, JP ;
GORMAN, CB ;
LAIBINIS, PE ;
BUCHHOLZ, S ;
WHITESIDES, GM ;
NUZZO, RG .
LANGMUIR, 1995, 11 (03) :813-824
[9]   Bonding self-assembled, compact organophosphonate monolayers to the native oxide surface of silicon [J].
Hanson, EL ;
Schwartz, J ;
Nickel, B ;
Koch, N ;
Danisman, MF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (51) :16074-16080
[10]   Low-voltage polymer field-effect transistors gated via a proton conductor [J].
Herlogsson, Lars ;
Crispin, Xavier ;
Robinson, Nathaniel D. ;
Sandberg, Mats ;
Hagel, Olle-Jonny ;
Gustafsson, Goran ;
Berggren, Magnus .
ADVANCED MATERIALS, 2007, 19 (01) :97-+