Low-voltage high-performance C60 thin film transistors via low-surface-energy phosphonic acid monolayer/hafnium oxide hybrid dielectric
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Acton, Orb
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Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USAUniv Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
Acton, Orb
[1
]
Ting, Guy
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Univ Washington, Dept Chem, Seattle, WA 98195 USAUniv Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
Ting, Guy
[2
]
Ma, Hong
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Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
Univ Washington, Inst Adv Mat & Technol, Seattle, WA 98195 USAUniv Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
Ma, Hong
[1
,3
]
Jen, Alex K. -Y.
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Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
Univ Washington, Dept Chem, Seattle, WA 98195 USA
Univ Washington, Inst Adv Mat & Technol, Seattle, WA 98195 USAUniv Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
Jen, Alex K. -Y.
[1
,2
,3
]
机构:
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
[3] Univ Washington, Inst Adv Mat & Technol, Seattle, WA 98195 USA
C(60)-based organic thin film transistors (OTFTs) have been fabricated using a n-octadecylphosphonic acid self-assembled monolayer/ sol-gel processed hafnium oxide hybrid dielectric. With the combination of high capacitance (580 nF/cm(2)) and low leakage current density (8 x 10(-9) A/cm(2)), this hybrid dielectric yields C(60) OTFTs operating under 1.5 V with an average n-channel saturation field-effect mobility of 0.28 cm(2)/V s, high on-off current ratio of 105, and low subthreshold slope of 100 mV/decade. The low surface energy of the n-octadecylphosphonic acid allows C(60) to form a thin film with large grains that provide an efficient charge carrier pathway for the low-voltage OTFTs. (c) 2008 American Institute of Physics.